Capoliveri is a comune (municipality) on the island of Elba in Italy. Administratively it is part of the Province of Livorno in the Tuscany region, located about 130 km southwest of Florence and about 90 km south of Livorno. As of 31 December 2004, it had a population of 3,427 and an area of 39.0 km². Capoliveri borders the following municipalities: Campo nell'Elba, Porto Azzurro, Portoferraio.